Role of virial coefficients in chemical reaction

نویسندگان

چکیده

van’t Hoff equation relates equilibrium constant K of a chemical reaction to temperature T. Though the plot ( $$\ln K$$ vs. 1/T) is linear, it nonlinear for certain reactions. In this work we attribute such observations virial coefficients.

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ژورنال

عنوان ژورنال: Pramana

سال: 2021

ISSN: ['0304-4289', '0973-7111']

DOI: https://doi.org/10.1007/s12043-021-02185-y